Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers.

نویسندگان

  • Stefan Spirk
  • Raphael J F Berger
  • Christian G Reuter
  • Rudolf Pietschnig
  • Norbert W Mitzel
چکیده

The first gas phase structure of a silanetriol, tert-butylsilane-triol [(t)BuSi(OH)(3)], determined by gas electron diffraction (GED), is reported. Quantum chemical calculations have been performed to elucidate potential intermolecular interactions between silanetriol molecules in the gas phase. The results are set into contrast to solid state structures of (t)BuSi(OH)(3) and related compounds.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 13  شماره 

صفحات  -

تاریخ انتشار 2012